In the castle of Enchancia:

• Royalties: Princess Sofia | Princess Amber | Prince James | King Roland II | Queen Lorelei | Queen Miranda | Aunt Tilly (Duchess Matilda) | Grand Mum | King Roland I
  
• Castle Staff: Baileywick the Castle Steward | Cedric the Sorcerer | Violet | Suzette | Marcy | Constable Myles | Armstrong | Gwen | Chef Andre
  

At Royal Preparatory Academy:

• Students: Princess Hildegard | Princess Clio | Princess Maya | Prince Zandar | Prince Desmond | Prince Hugo | Princess Jun | Prince Jin | Princess Vivian | Princess Leena | Prince Khalid | Princess Zooey | Princess Kari | Prince Derek | Princess Astrid
  
• Teachers: Flora, Fauna and Merryweather | Professor Popov | Mrs. Higgins | Sir Gilliam | Miss Elodie | Sir Henley | Professor Pecullian
  

At Charmswell School:

• Students: Princess Layla | Princess Camila | Prince Zane | Prince Devin | Princess Zaria | Princess Thandi | Prince Haruki | Prince Farhad | Prince Reginald | Princess Mayari | Princess Linh | Prince Rufus
  
• Teachers: Miss Nettle | Miss Gigglesby | Lady Saddlespur | Lord Primrose | Mr. Muddykins
  

Other Royalties: King Marcus and Queen Cecily | King Magnus | Emperor Quon | Empress Lin-Lin | Queen Anya | King Garrick | Oona | Queen Emmaline | Cora | Lord Gilbert | Lady Joy | Princess Lani | Kamea and Halia | Queen Avery | King Habib and Queen Farnaz | Queen Tessa | King Oberlyn | Prince Roderick | Prince Derek | Sir Henley | King Henrik | King of Brazendell | Princess Charlotte | King Philip and Queen Everly | Princess Cassandra
Villagers of Dunwiddie: Jade | Ruby | Lucinda | Helen Hanshaw | Meg and Peg | Carol of the Arrow | Jane | Marla | Luciano | Lily | Indigo
Outside Enchancia: Vaughan and Vance | Goodwyn the Great | Winifred the Wise | Boswell | Madam Ubetcha | Sir Bartleby | Sir Maxwell | Sir Finnegan | Winter | Wendell Fidget | Mrs. Fidget | Spruce | Cordelia the Conjuror | Calista | Elfonso | Elfred | Elliot, Amy, and Kurt | Professor Zacharias Fleeber | Sir Jaxon | Zinessa | Marty and Maple | Mandy | Captain Quivers | Giant
Magical Beings: Miss Nettle | Sir Dax | Boo | Glacia the Ice Witch | Plank | Fluke | Slim | Shelly | Flip | Kazeem | Sergeant Fizz | Azurine | Orion | Vega | Chrysta | Sugar Plum Fairy | Flurry | Bridget | Nerissa | Elfabelle | Arielf
Animals: Clover | Robin | Mia | Whatnaught | Wormwood | Minimus | Lulu | Praline | Freedo | Ginger | Electra | Lawrence | Director Dove | Farley | Sven | Rex | Whiskers | Saffron | Mazzimo | Flinch | Herb the Hedgehog | Milo the Snake | Barley | Sassofras | Kai | Gemina and Argus | Wriggley, Pumpkin, and Chester | Piccolo | Roma
Dragons: Crackle | Dragons of Enchancia | Willawing | Crispy | Sizzle | Cinder | The Duchess
Creatures: Gnarly | Trolls | Teeny | Jasper | Wilbur the Wombeast | Crankle the Ogre | Jade Jaguar | Mantacorn | Grotta | Button, Benngee and Brody | Onyx and Opal | Mossy | Muck, Gunk, and Grime | Morris | Sea Monsters | Malacite and Fig | Skye | Mare of the Mist | Giggling Goblin | Hidey | Humbelle and Blaze | Buzzer | Pepper | Wildfyre
Antagonist: Sofia the Worst | Slickwell | Mamanu | Princess Ivy | Sir Oliver | Morgana | Grimtrix | Crispy | Greylock the Grand | Omar | Baron Von Rocha | Prisma | Twitch | Sphinx | Vor | Zandrya | Mimsy Fizzlewick
Disney Princesses: Cinderella | Jasmine | Belle | Ariel | Aurora | Snow White | Mulan | Rapunzel | Tiana | Merida | Moana
Elena of Avalor: Princess Elena | Princess Isabel | Francisco | Luisa | Shuriki | Alakazar | Zuzo | Mateo | Migs, Luna, and Skylar | Rafa | Chancellor Esteban | Naomi Turner | Armando | King Raul and Queen Lucia
Guest Characters:: Magic Carpet | Olaf | Merlin | Maximus
Unseen Mentioned Characters: Birk Balthazar | Prince Charming | Prince Adam/Beast | Prince Eric | Evil Queen | Flynn Rider | Mama Odie | Fairy Godmother